Sunday Meet the Press hosts Senate Majority Whip Dick Durbin, Senate Minority Whip Jon Kyl, and Romney senior adviser Ed Gillespie. Face the Nation hosts Rep. Paul Ryan, R-Wis., Obama deputy campaign manager Stephanie Cutter and Romney adviser Kevin Madden. This Week hosts Chicago Mayor Rahm Emanuel and Sen. Kelly Ayotte, R-N.H. Fox News Sunday hosts Florida Gov. Rick Scott and Iowa Gov. Terry Branstad. State of the Union hosts Virginia Gov. Bob McDonnell, Massachusetts Gov. Deval Patrick, Romney senior adviser Ed Gillespie and Agriculture Secretary Tom Vilsack. Other Weekend Shows Political Capital features Priorities USA founder Bill Burton (Bloomberg, Friday, 9 p.m.). Washington Week features Time's Michael Duffy, Washington Post's Lori Montgomery, RealClearPolitics' Alexis Simendinger and Reuters' Sam Youngman (PBS, Friday, 8 p.m.). Real Time is on break (HBO, Friday, 10 p.m.). Situation Room features a best of the week (CNN, Saturday, 6:30 p.m.). Communicators features the Capitol Hill technology fair (C-SPAN, Saturday, 6:30 p.m.). Chris Matthews Show features Time's Michael Duffy, MSNBC's Andrea Mitchell, Huffington Post's Howard Fineman and AP's Kasie Hunt (NBC, Sunday, check local listings). Newsmakers features Rep. Kevin Brady, R-Texas (C-SPAN, Sunday, 10 a.m./6 p.m.). Reliable Sources features Chicago Tribune's Clarence Page, Washington Post's Jennifer Rubin, RealClearPolitics' Erin McPike, Tyndal Report's Andrew Tyndall, Quinnipiac's Paul Friedman, PandoDaily.com's Sarah Lacy and Columbia University's Sree Sreenivasan (CNN, Sunday, 11 a.m.). Fareed Zakaria GPS features Syrian National Council president Abdulbaset Sieda, the Economist's Zanny Minton Beddoes, Reuters' Chrystia Freeland, author Zachary Karabell, CNBC's Larry Kudlow and astrophysicist Neil deGrasse Tyson (CNN, Sunday, 10 a.m.). Q & A features author Antony Beevor (C-SPAN, Sunday, 8 p.m.). Al Punto features an interview with First Lady Michelle Obama, former Mexico presidential candidate Santiago Creel and musicians Juan Andres and Nicolas Ospina (UNIVISION, Sunday, 10 a.m.).